Sodium Bismuthate: An Efficient Catalyst for the One-pot Synthesis of Biologically Active Spiro[4H-pyran] Derivativesunder Solvent-free Conditions

Authors

  • Farzaneh Mohamadpour Department of Chemistry, Faculty of Science, University of Sistan and Baluchestan, Zahedan,Iran
  • Mojtaba Lashkari Department of Chemistry, Faculty of Science, University of Sistan and Baluchestan, Zahedan, Iran
  • Reza Heydari Department of Chemistry, Faculty of Science, University of Sistan and Baluchestan, Zahedan, Iran
Abstract:

An efficient sodium bismuthate (NaBiO3) synthesis of biologically active spiro[4H-pyran]derivatives has been accomplished via one-pot three-condensation of isatin/acenaphthequinone, malononitrile and different reagents including 1,3-dicrbonyl compounds, α-naphthol and 4-hydroxycumarin under solvent-free conditions. The notable advantages of the present procedure are: eco-friendly, environmentally benign nature,low-cost and non-toxic catalyst, simplicity of operation with no necessity of chromatographicpurification steps, short reaction times, good to high yields and solvent-free conditions.

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Journal title

volume 11  issue 3

pages  46- 57

publication date 2017-09-01

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